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- W2951775703 abstract "The rates of proton transfer from 2, 4-hexadiene, 1, 3-cycloheptadiene, cyclopentadiene and acetone to t-butoxide have been measured in the gas phase using pulsed-ion-cyclotron-resonance spectroscopy. The rate constants are (units of 10−10 cm3 molecule−1 s−1): 2.7 ± 0.4, 3.8 ± 0.4, 6.1 ± 0.7 and 10.8 ± 1.5, respectively. These results are analyzed in terms of the properties of the encounter complex and reaction transition states. The reaction profile for t-butoxide + cyclopentadiene is modeled using RRKM theory and an estimate for the central barrier height is obtained." @default.
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- W2951775703 date "1981-10-13" @default.
- W2951775703 modified "2023-09-25" @default.
- W2951775703 title "ChemInform Abstract: RATES OF PROTON ABSTRACTION FROM CONJUGATED DIENES IN THE GAS PHASE" @default.
- W2951775703 cites W2020563682 @default.
- W2951775703 doi "https://doi.org/10.1002/chin.198141112" @default.
- W2951775703 hasPublicationYear "1981" @default.
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