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- W2951779891 abstract "The crystal structure of the title compound, cadmium sulfate monohydrate or poly[(μ2-aqua)(μ4-sulfato)cadmium], was redetermined based on modern CMOS (complementary metal oxide silicon) data. In comparison with the previous study [Bregeault & Herpin (1970). Bull. Soc. Fr. Mineral. Cristallogr. 93, 37–42], all non-H atoms were refined with anisotropic displacement parameters and the hydrogen-bonding pattern unambiguously established due to location of the hydrogen atoms. In addition, a significant improvement in terms of precision and accuracy was achieved. In the crystal, the Cd2+ cation is coordinated by four O atoms of four sulfate anions and two O atoms of water molecules, forming a distorted octahedral trans-[CdO6] polyhedron. Each sulfate anion bridges four Cd2+ cations and each water molecule bridges two Cd2+ cations, leading to the formation of a three-dimensional framework, with Cd⋯Cd separations in the range 4.0757 (2)–6.4462 (3) A. O—H⋯O hydrogen-bonding interactions of medium strength between the coordinating water molecules and sulfate anions consolidate the crystal packing." @default.
- W2951779891 created "2019-06-27" @default.
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- W2951779891 date "2016-01-01" @default.
- W2951779891 modified "2023-09-27" @default.
- W2951779891 title "ChemInform Abstract: Crystal Structure of CdSO4(H2O): A Redetermination." @default.
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- W2951779891 doi "https://doi.org/10.1002/chin.201601002" @default.
- W2951779891 hasPublicationYear "2016" @default.
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