Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951781060> ?p ?o ?g. }
- W2951781060 endingPage "3244" @default.
- W2951781060 startingPage "3237" @default.
- W2951781060 abstract "Flux growth is a promising method that allows one to control over the crystalline phase, crystal shape, crystal size, and crystal surface through the selection of a suitable flux. In this work, lanthanum titanate (La2Ti2O7) crystals with different morphologies were grown using the Na2MoO4, K2MoO4, NaCl, and mixed NaCl + K2MoO4 (molar ratio = 3:7) fluxes, and their nitridability to form LaTiO2N crystals under a high-temperature NH3 atmosphere was also investigated. The effects of the solute concentration and cooling rate on the growth of the La2Ti2O7 crystals were also studied. The X-ray diffraction results revealed that the {100} plane was dominant in the La2Ti2O7 platelet crystals grown using the alkali-metal molybdate fluxes. When the solute concentration was increased from 1 to 20 mol %, the average size of the crystals decreased without considerable alteration of the overall crystal morphology. The La2Ti2O7 crystals with the preferred ⟨010⟩ and ⟨001⟩ growth directions along the b and c axes were grown using the Na2MoO4 and K2MoO4 fluxes, respectively. Compared to the Na2MoO4 flux, the K2MoO4 flux did not show a cooling-rate-dependent effect on the growth of the La2Ti2O7 crystals. It was found that conversion of the La2Ti2O7 crystals to the LaTiO2N crystals was strongly dependent on the flux used to grow the precursor La2Ti2O7 crystals. That is, the La2Ti2O7 crystals grown using the K2MoO4 and NaCl fluxes were nearly completely converted into the LaTiO2N crystals, while conversion of the La2Ti2O7 crystals grown using the Na2MoO4 and mixed NaCl + K2MoO4 fluxes to the LaTiO2N crystals seemed to be not completed yet even after nitridation at 950 °C for 15 h using NH3 because of the larger crystal size and the presence of unintentional impurities (sodium and molybdenum from the flux) in the La2Ti2O7 crystal lattice. Nevertheless, the LaTiO2N crystals fabricated by nitriding the La2Ti2O7 crystals grown using the K2MoO4 and NaCl fluxes should be suitable for direct solar water splitting." @default.
- W2951781060 created "2019-06-27" @default.
- W2951781060 creator A5023425340 @default.
- W2951781060 creator A5039972852 @default.
- W2951781060 creator A5043084960 @default.
- W2951781060 creator A5072246252 @default.
- W2951781060 creator A5073005243 @default.
- W2951781060 date "2015-03-19" @default.
- W2951781060 modified "2023-10-18" @default.
- W2951781060 title "Fabrication of La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> Crystals Using an Alkali-Metal Molybdate Flux Growth Method and Their Nitridability To Form LaTiO<sub>2</sub>N Crystals under a High-Temperature NH<sub>3</sub> Atmosphere" @default.
- W2951781060 cites W1965571863 @default.
- W2951781060 cites W1967938767 @default.
- W2951781060 cites W1971272463 @default.
- W2951781060 cites W1994102145 @default.
- W2951781060 cites W1994213467 @default.
- W2951781060 cites W1997839374 @default.
- W2951781060 cites W2002629142 @default.
- W2951781060 cites W2005543514 @default.
- W2951781060 cites W2014176062 @default.
- W2951781060 cites W2014514745 @default.
- W2951781060 cites W2030953722 @default.
- W2951781060 cites W2030965166 @default.
- W2951781060 cites W2034643761 @default.
- W2951781060 cites W2037865127 @default.
- W2951781060 cites W2049029113 @default.
- W2951781060 cites W2057076961 @default.
- W2951781060 cites W2062387372 @default.
- W2951781060 cites W2065961397 @default.
- W2951781060 cites W2072089377 @default.
- W2951781060 cites W2073471133 @default.
- W2951781060 cites W2074852616 @default.
- W2951781060 cites W2089085132 @default.
- W2951781060 cites W2090897652 @default.
- W2951781060 cites W2093306535 @default.
- W2951781060 cites W2093821842 @default.
- W2951781060 cites W2097036884 @default.
- W2951781060 cites W2099668530 @default.
- W2951781060 cites W2109372467 @default.
- W2951781060 cites W2145315636 @default.
- W2951781060 cites W2315057599 @default.
- W2951781060 cites W2322403516 @default.
- W2951781060 cites W2323524882 @default.
- W2951781060 cites W2326845365 @default.
- W2951781060 cites W2328465982 @default.
- W2951781060 cites W2329290176 @default.
- W2951781060 cites W2329782556 @default.
- W2951781060 cites W2330861997 @default.
- W2951781060 cites W2332593067 @default.
- W2951781060 cites W2334544419 @default.
- W2951781060 cites W2626158726 @default.
- W2951781060 cites W2949230452 @default.
- W2951781060 cites W2950098031 @default.
- W2951781060 cites W2952698715 @default.
- W2951781060 doi "https://doi.org/10.1021/ic502862t" @default.
- W2951781060 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25789564" @default.
- W2951781060 hasPublicationYear "2015" @default.
- W2951781060 type Work @default.
- W2951781060 sameAs 2951781060 @default.
- W2951781060 citedByCount "37" @default.
- W2951781060 countsByYear W29517810602015 @default.
- W2951781060 countsByYear W29517810602016 @default.
- W2951781060 countsByYear W29517810602017 @default.
- W2951781060 countsByYear W29517810602018 @default.
- W2951781060 countsByYear W29517810602019 @default.
- W2951781060 countsByYear W29517810602020 @default.
- W2951781060 countsByYear W29517810602021 @default.
- W2951781060 countsByYear W29517810602022 @default.
- W2951781060 countsByYear W29517810602023 @default.
- W2951781060 crossrefType "journal-article" @default.
- W2951781060 hasAuthorship W2951781060A5023425340 @default.
- W2951781060 hasAuthorship W2951781060A5039972852 @default.
- W2951781060 hasAuthorship W2951781060A5043084960 @default.
- W2951781060 hasAuthorship W2951781060A5072246252 @default.
- W2951781060 hasAuthorship W2951781060A5073005243 @default.
- W2951781060 hasConcept C113196181 @default.
- W2951781060 hasConcept C178790620 @default.
- W2951781060 hasConcept C179104552 @default.
- W2951781060 hasConcept C185592680 @default.
- W2951781060 hasConcept C198091228 @default.
- W2951781060 hasConcept C199360897 @default.
- W2951781060 hasConcept C26456737 @default.
- W2951781060 hasConcept C2775981058 @default.
- W2951781060 hasConcept C2778320197 @default.
- W2951781060 hasConcept C2781285689 @default.
- W2951781060 hasConcept C41008148 @default.
- W2951781060 hasConcept C43617362 @default.
- W2951781060 hasConcept C68709404 @default.
- W2951781060 hasConcept C73922627 @default.
- W2951781060 hasConcept C8010536 @default.
- W2951781060 hasConceptScore W2951781060C113196181 @default.
- W2951781060 hasConceptScore W2951781060C178790620 @default.
- W2951781060 hasConceptScore W2951781060C179104552 @default.
- W2951781060 hasConceptScore W2951781060C185592680 @default.
- W2951781060 hasConceptScore W2951781060C198091228 @default.
- W2951781060 hasConceptScore W2951781060C199360897 @default.
- W2951781060 hasConceptScore W2951781060C26456737 @default.
- W2951781060 hasConceptScore W2951781060C2775981058 @default.
- W2951781060 hasConceptScore W2951781060C2778320197 @default.