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- W2951781498 abstract "The reaction of piperdin-2-ones with a 2-bromobenzyl substituent in the 5-position in the presence of a palladium catalyst leads to biaryl compounds. Their formation can be explained via initial C−H insertion of the aryl palladium species into the allylic C−H bond of the piperidinone. This eventually leads to a metallacycle containing Pd(II) that inserts another aryl bromide, promoting the formation of the biaryl bond." @default.
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- W2951781498 date "2008-05-21" @default.
- W2951781498 modified "2023-09-23" @default.
- W2951781498 title "Biaryl Formation from 5-(2-Bromobenzyl)-Substituted Piperidin-2-ones via Palladacycles" @default.
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- W2951781498 doi "https://doi.org/10.1021/ol800330d" @default.
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