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- W2951802703 abstract "Six different rare-earth oxyapatites, including Ca 2 RE 8 (SiO 4 ) 6 O 2 ( RE = La, Nd, Sm, Eu, or Yb) and NaLa 9 (SiO 4 ) 6 O 2 , were synthesized using solution-based processes followed by cold pressing and sintering. The crystal structures of the synthesized oxyapatites were determined from powder X-ray diffraction (P-XRD) and their chemistries verified with electron probe microanalysis (EPMA). All the oxyapatites were isostructural within the hexagonal space group P 6 3 / m and showed similar unit-cell parameters. The isolated [SiO 4 ] 4− tetrahedra in each crystal are linked by the cations at the 4 f and 6 h sites occupied by RE 3+ and Ca 2+ in Ca 2 RE 8 (SiO 4 ) 6 O 2 or La 3+ and Na + in NaLa 9 (SiO 4 ) 6 O 2 . The lattice parameters, cell volumes, and densities of the synthesized oxyapatites fit well to the trendlines calculated from literature values." @default.
- W2951802703 created "2019-06-27" @default.
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- W2951802703 date "2019-06-21" @default.
- W2951802703 modified "2023-09-27" @default.
- W2951802703 title "Syntheses, crystal structures, and comparisons of rare-earth oxyapatites Ca<sub>2</sub> <i>RE</i> <sub>8</sub>(SiO<sub>4</sub>)<sub>6</sub>O<sub>2</sub> (<i>RE</i> = La, Nd, Sm, Eu, or Yb) and NaLa<sub>9</sub>(SiO<sub>4</sub>)<sub>6</sub>O<sub>2</sub>" @default.
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- W2951802703 doi "https://doi.org/10.1107/s2056989019008442" @default.
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