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- W2951807327 abstract "We describe a palladium-catalyzed diastereo- and enantioselective formal [3 + 2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins in the form of azlactone- and Meldrum’s acid alkylidenes to give highly substituted cyclopentane products. By modulation of the electronic properties of the vinylcyclopropane and the electron-deficient olefin, high levels of stereoselectivity were obtained. The remote stereoinduction afforded by the catalyst, distal from the chiral pocket generated by the ligand, is proposed to be the result of a new mechanism invoking the Curtin–Hammett principle." @default.
- W2951807327 created "2019-06-27" @default.
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- W2951807327 date "2013-03-18" @default.
- W2951807327 modified "2023-09-27" @default.
- W2951807327 title "ChemInform Abstract: Palladium-Catalyzed Diastereo- and Enantioselective Formal [3 + 2]-Cycloadditions of Substituted Vinylcyclopropanes." @default.
- W2951807327 cites W2115827312 @default.
- W2951807327 doi "https://doi.org/10.1002/chin.201313041" @default.
- W2951807327 hasPublicationYear "2013" @default.
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