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• W2951818059 abstract "Optically active trialkylsilyllithiums, (R)-(n-butyl)methylphenylsilyllithium (63% ee) and (S)-methyl(1-naphthyl)phenylsilyllithium (96% ee), were prepared by cleavage of the siliconsilicon bond of (R)-1-(n-butyl)-1-methyl-1-phenyl-2,2-diphenyl-2-methyldisilane with lithium metal, or the silicontin bond of (S)-methyl(1-naphthyl)phenylsilyltrimethylstannane with methyllithium, respectively. Optical purity of the silyllithiums was evaluated as corresponding silanes by HPLC on optically active stationary phase after hydrolysis. The formation of silyllithium was found to be highly stereospecific (>94, >99% retention, respectively). (S)-Methyl(1-naphthyl)phenylsilyllithium is configurationally stable for at least 1 h at −78°C in tetrahydrofuran." @default.
• W2951818059 created "2019-06-27" @default.
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• W2951818059 date "2000-10-01" @default.
• W2951818059 modified "2023-10-17" @default.
• W2951818059 title "Stereospecific formation of optically active trialkylsilyllithiums and their configurational stability" @default.
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• W2951818059 doi "https://doi.org/10.1016/s0022-328x(00)00294-1" @default.
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