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- W2951827178 abstract "Abstract The relationship between the hydride phases in the LaNi5-H2 system was investigated using in situ X-ray diffraction measurements in hydrogen atmospheres at pressures of up to 5 MPa. A new hydride phase, denoted the γ hydride here, was observed in addition to the α and β phases in the region of the reaction plateau in the temperature range 40–95 °C. These three phases usually coexisted under these conditions. A single phase of the γ hydride was not observed but its X-ray diffraction spectrum was synthesized by computer to determine the crystal structure. The γ phase was indexed according to a hexagonal lattice with a = 5.28 A , c = 4.04 A and its composition was estimated to be close to LaNi5H4. The γ hydride was obviously different from LaNi5H6 which was generally believed to be the only hydride phase of the LaNi5-H2 system in the pressure range usually used. The hydrogen absorption-desorption cycles had a marked effect on the stability of the γ hydride. After many cycles the γ phase became more stable." @default.
- W2951827178 created "2019-06-27" @default.
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- W2951827178 date "1987-01-13" @default.
- W2951827178 modified "2023-09-24" @default.
- W2951827178 title "ChemInform Abstract: A New Intermediate Hydride in the LaNi5-H2 System Studied by in situ X-Ray Diffractometry." @default.
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- W2951827178 doi "https://doi.org/10.1002/chin.198702023" @default.
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