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- W2951828077 abstract "Optically active silanes were synthesized by a novel asymmetric synthesis which involved the diastereoselective ring-opening reaction of 1,3-dioxa-2-silacycloheptanes bearing a C2 chiral auxiliary with Grignard reagents, followed by a lithium aluminum hydride (LiAlH4) reduction. (R)-Ethylmethylphenylsilane and (R)-methylphenylpropylsilane were derived in 93%ee and 98%ee, respectively. The preparation of the other optical silanes is also described. The maximum rotations of some of them have been determined by 1H NMR and/or capillary GC methods. A mechanism for a diastereoselective ring-opening reaction is proposed based on the stereochemical results." @default.
- W2951828077 created "2019-06-27" @default.
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- W2951828077 date "2010-08-03" @default.
- W2951828077 modified "2023-09-26" @default.
- W2951828077 title "ChemInform Abstract: Asymmetric Synthesis of Organosilicon Compounds Using a C2 Chiral Auxiliary." @default.
- W2951828077 cites W2028183247 @default.
- W2951828077 doi "https://doi.org/10.1002/chin.199740206" @default.
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