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- W2951836872 abstract "A novel synthesis of fluoroolefins from trifluoromethylated compounds with organometallic reagents was developed. The reaction seems to proceed via 1,4-alkylation on imino nitrogen followed by defluorination of the trifluoromethyl group. Diethylzinc was found to be an efficient reagent for the preparation of 2-(N-aryl-N-ethyl)amino-3,3-difluoropropenoates in excellent yield. A similar synthesis of monofluoroolefin with Grignard reagent was also developed." @default.
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- W2951836872 date "2010-08-05" @default.
- W2951836872 modified "2023-09-26" @default.
- W2951836872 title "ChemInform Abstract: Tandem Alkylation-Defluorination Reaction: Synthesis of 2-(N-Alkyl-N- aryl)amino-3,3-difluoropropenoates from 2-(N-Aryl)imino-3,3,3- trifluoropropanoates." @default.
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- W2951836872 doi "https://doi.org/10.1002/chin.199627118" @default.
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