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- W2951843627 abstract "The complex [Tl(CH3)2(L)]ClO4 was prepared from tridecalino-18-crown-6 {1,4,15,18,29,32-hexaoxaperhydro[4.4.4](4a,8a) naphthalenophane}(L) and dimethylthallium(III) perchlorate. The molecular structure has been determined by single-crystal X-ray diffraction methods. The O6 hexagon of the crown ether is planar within 0.05 A and the decalin moieties apparently construct a cylinder wall. The linear dimethylthallium(III) ion penetrates into the centre of the O6 hexagon with six equal Tl–O bonds and the decalin walls are in contact with methyl groups of the dimethylthallium(III) ion." @default.
- W2951843627 created "2019-06-27" @default.
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- W2951843627 date "1987-04-28" @default.
- W2951843627 modified "2023-09-24" @default.
- W2951843627 title "ChemInform Abstract: Dimethylthallium(III) Complex of a Cylindrical Crown Ether: Molecular Structure of (Tl(CH3)2(L))ClO4." @default.
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- W2951843627 doi "https://doi.org/10.1002/chin.198717269" @default.
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