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- W2951844106 abstract "Orange crystals of Cs4Th4P4Se26 were grown from the reaction of 232Th and P in a Cs2Se3/Se molten salt flux at 750 °C. Cs4Th4P4Se26 crystallizes in the orthorhombic space group Pbca with the unit cell parameters: a = 12.0130(6), b = 14.5747(7), c = 27.134(1) Å; Z = 8. The compound exhibits a three-dimensional structure, consisting of dimeric [Th2Se13] polyhedral units. The two crystallographically independent, nine-coordinate, bicapped trigonal prismatic thorium atoms share a triangular face to form the dimer, and each dimer edge-shares two selenium atoms with two other dimers to form kinked chains along the [010] direction. While this structure shares features of the previously reported Rb4U4P4Se26, including phosphorus in the 5+ oxidation state, careful inspection of the structure reveals that the selenophosphate anion that knits the structure together in three directions in both compounds is a unique (P2Se9)6- anion. The formula may be described best as [Cs2Th2(P2Se9)(Se2)2]2. The (P2Se9)6- anion features a nearly linear Se−Se−Se backbone with an angle of 171° and Se−Se distances that are approximately 0.2−0.3 Å longer than the typical single Se−Se bond. Magnetic studies confirm that this phase contains Th(IV). Raman data for this compound is reported, and structural comparisons will be drawn to its uranium analogue, Rb4U4P4Se26." @default.
- W2951844106 created "2019-06-27" @default.
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- W2951844106 date "2001-08-09" @default.
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- W2951844106 title "Synthesis, Structure, and Properties of Cs<sub>4</sub>Th<sub>4</sub>P<sub>4</sub>Se<sub>26</sub>: A Quaternary Thorium Selenophosphate Containing the (P<sub>2</sub>Se<sub>9</sub>)<sup>6</sup><sup>-</sup> Anion" @default.
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- W2951844106 doi "https://doi.org/10.1021/ic001103l" @default.
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