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- W2951844197 abstract "Abstract The hydrosilylation of ethynylsilanes RCCH (R = Me 3 Si. Cl 3 Si, Cl 3 Si, (EtO) 3 Si, N(CH 2 CH 2 O) 3 Si ) in the presence of Speier's catalyst gives predominantly the β- trans -isomer, which in the case of ethynylsilatrane is the only product formed. The reaction of trimethylethynylsilane and its carbon analogue, t-butylacetylene, with dimethyl(2-thienyl)silane in the presence of rhodium catalyst occurs less selectively to afford both the hydroxilylation products and the products of dehydrocondensation. In some cases, a product of double bond hydrogenation is also formed." @default.
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- W2951844197 date "1988-11-01" @default.
- W2951844197 modified "2023-09-23" @default.
- W2951844197 title "ChemInform Abstract: Hydrosilylation of Ethynylsilanes with Dimethyl(2-thienyl)silane." @default.
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- W2951844197 doi "https://doi.org/10.1002/chin.198844229" @default.
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