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- W2951845110 endingPage "4769" @default.
- W2951845110 startingPage "4766" @default.
- W2951845110 abstract "A simple domino process for the construction of the tricyclic core present in the spiro-pseudoindoxyl natural products has been developed. This involves two intramolecular events: the Au-catalyzed nitroalkyne redox leading to isatogen and its subsequent [3 + 2]-cycloaddition with a suitably positioned olefin. The option to modulate the size of the spiro-annulated ring, which is an important variable in this class of natural products, has been explored. Overall, this process molds a linear precursor into a tricyclic system with complete step, atom, and redox economy." @default.
- W2951845110 created "2019-06-27" @default.
- W2951845110 creator A5049776185 @default.
- W2951845110 creator A5078456641 @default.
- W2951845110 date "2014-08-28" @default.
- W2951845110 modified "2023-10-07" @default.
- W2951845110 title "Tuning the Regioselectivity of Gold-Catalyzed Internal Nitroalkyne Redox: A Cycloisomerization and [3 + 2]-Cycloaddition Cascade for the Construction of <i>spiro</i>-Pseudoindoxyl Skeleton" @default.
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- W2951845110 doi "https://doi.org/10.1021/ol502213w" @default.
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- W2951845110 hasPublicationYear "2014" @default.
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