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- W2951845947 abstract "The rheological behavior and crystallization behavior of high density polyethylene (HDPE) and polyethylene (PE) oligomer (HDPE/PE oligomer) and polypropylene (PP) and polyethylene oligomer (PP/PE oligomer) binary blends were investigated in this study. Batch processing along with rheological model experiments revealed that molecular diffusion is the dominating mechanism in the homogenization of such blends. Further rheological characterization and modeling (using the Carreau-Yasuda equation) allowed to demonstrate that the PE oligomer is miscible in both polymers, but that saturation may occur at high concentrations. Thermal analysis as well as polarized light and electronic microscopy showed that both systems undergo solid-liquid phase separation upon cooling, with direct consequences on the mechanical properties of the blends. The concentrations at which saturation (in the melt), phase separation (upon cooling), and degradation of the mechanical properties occur were found to be dependent on the nature of the polymer; around 20 to 30 wt% for HDPE and 5 to 10 wt% in the case of PP." @default.
- W2951845947 created "2019-06-27" @default.
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- W2951845947 date "2019-08-01" @default.
- W2951845947 modified "2023-10-18" @default.
- W2951845947 title "Rheology and crystallization behavior of polypropylene and high‐density polyethylene in the presence of a low molar mass polyethylene" @default.
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- W2951845947 doi "https://doi.org/10.1002/pcr2.10078" @default.
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