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• W2951868967 abstract "The crystallographic structures of many U2TSi3 compounds with T a transition element were investigated by both X-ray and electron diffraction studies. These silicides crystallize in the ideal or derivative structure of the hexagonal AIB2 type. A structural ordering between T and Si atoms exists in these various compounds; it is strongly influenced by the nature of the transition element. This structural ordering seems to be attributed to an electronic factor rather than to a steric factor; it is favoured with T elements having a small number of d electrons. Furthermore, these compounds exhibit interesting magnetic properties since for T = Fe, Ru and Os, they display a spin fluctuation behaviour at low temperatures whereas for T = Co, Ni, Rh, Pd, Ir, Pt and Au they order magnetically." @default.
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• W2951868967 date "1996-01-01" @default.
• W2951868967 modified "2023-10-18" @default.
• W2951868967 title "Structural chemistry and magnetic behaviour of the ternary silicides U2TSi3 (T = Mn, Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt, Au)" @default.
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• W2951868967 doi "https://doi.org/10.1016/0925-8388(95)02006-3" @default.
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