FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951870155> ?p ?o ?g. }

• W2951870155 endingPage "7941" @default.
• W2951870155 startingPage "7935" @default.
• W2951870155 abstract "A new self-assembled catalyst based on titanium complex has been developed for the effective enantioselective cyano-ethoxycarbonylation of aldehydes. The self-assembled catalyst was readily prepared from (R)-3,3′-bis((methyl((S)-1-phenylethyl)amino)methyl)-1,1′-binaphthyl-2,2′-diol (1h), N-((1S,2R)-2-hydroxy-1,2-diphenylethyl)acetamide (2b), and tetraisopropyl titanate (Ti(OiPr)4). A variety of aromatic aldehydes, aliphatic aldehydes, and α,β-unsaturated aldehydes were found to be suitable substrates in the presence of the self-assembled titanium catalyst (5 mol % 1h, 5 mol % 2b, and 5 mol % Ti(OiPr)4). The desired cyanohydrin ethyl carbonates were afforded with high isolated yields (up to 95%) and moderate to good enantioselectivities (up to 92% ee) under mild conditions (at −15 °C). A possible catalytic cycle based on the experimental observation was proposed." @default.
• W2951870155 created "2019-06-27" @default.
• W2951870155 creator A5000139528 @default.
• W2951870155 creator A5002614379 @default.
• W2951870155 creator A5032926098 @default.
• W2951870155 creator A5077217676 @default.
• W2951870155 date "2007-08-01" @default.
• W2951870155 modified "2023-10-15" @default.
• W2951870155 title "Asymmetric cyano-ethoxycarbonylation of aldehydes catalyzed by self-assembled titanium catalyst" @default.
• W2951870155 cites W1973232162 @default.
• W2951870155 cites W1985422931 @default.
• W2951870155 cites W1991683498 @default.
• W2951870155 cites W1998607918 @default.
• W2951870155 cites W2006640815 @default.
• W2951870155 cites W2007833097 @default.
• W2951870155 cites W2016128288 @default.
• W2951870155 cites W2017338816 @default.
• W2951870155 cites W2020334062 @default.
• W2951870155 cites W2022057154 @default.
• W2951870155 cites W2051952747 @default.
• W2951870155 cites W2053052130 @default.
• W2951870155 cites W2065880092 @default.
• W2951870155 cites W2071739223 @default.
• W2951870155 cites W2093495633 @default.
• W2951870155 cites W2104911448 @default.
• W2951870155 cites W2110883543 @default.
• W2951870155 cites W2123790081 @default.
• W2951870155 cites W2124145731 @default.
• W2951870155 cites W2124567005 @default.
• W2951870155 cites W2125102654 @default.
• W2951870155 cites W2140930801 @default.
• W2951870155 cites W2146475319 @default.
• W2951870155 cites W2155619548 @default.
• W2951870155 cites W2156346041 @default.
• W2951870155 cites W2157397846 @default.
• W2951870155 cites W2162197069 @default.
• W2951870155 cites W2162227117 @default.
• W2951870155 cites W2949422677 @default.
• W2951870155 cites W2950913668 @default.
• W2951870155 cites W2951212424 @default.
• W2951870155 cites W2951822657 @default.
• W2951870155 cites W2951996506 @default.
• W2951870155 cites W2952170754 @default.
• W2951870155 cites W2952487039 @default.
• W2951870155 cites W4211197532 @default.
• W2951870155 doi "https://doi.org/10.1016/j.tet.2007.05.060" @default.
• W2951870155 hasPublicationYear "2007" @default.
• W2951870155 type Work @default.
• W2951870155 sameAs 2951870155 @default.
• W2951870155 citedByCount "28" @default.
• W2951870155 countsByYear W29518701552012 @default.
• W2951870155 countsByYear W29518701552013 @default.
• W2951870155 countsByYear W29518701552014 @default.
• W2951870155 countsByYear W29518701552015 @default.
• W2951870155 countsByYear W29518701552016 @default.
• W2951870155 countsByYear W29518701552019 @default.
• W2951870155 countsByYear W29518701552020 @default.
• W2951870155 crossrefType "journal-article" @default.
• W2951870155 hasAuthorship W2951870155A5000139528 @default.
• W2951870155 hasAuthorship W2951870155A5002614379 @default.
• W2951870155 hasAuthorship W2951870155A5032926098 @default.
• W2951870155 hasAuthorship W2951870155A5077217676 @default.
• W2951870155 hasConcept C126661725 @default.
• W2951870155 hasConcept C146686406 @default.
• W2951870155 hasConcept C155647269 @default.
• W2951870155 hasConcept C161790260 @default.
• W2951870155 hasConcept C178790620 @default.
• W2951870155 hasConcept C185592680 @default.
• W2951870155 hasConcept C2776730177 @default.
• W2951870155 hasConcept C2778910044 @default.
• W2951870155 hasConcept C2779515768 @default.
• W2951870155 hasConcept C506065880 @default.
• W2951870155 hasConceptScore W2951870155C126661725 @default.
• W2951870155 hasConceptScore W2951870155C146686406 @default.
• W2951870155 hasConceptScore W2951870155C155647269 @default.
• W2951870155 hasConceptScore W2951870155C161790260 @default.
• W2951870155 hasConceptScore W2951870155C178790620 @default.
• W2951870155 hasConceptScore W2951870155C185592680 @default.
• W2951870155 hasConceptScore W2951870155C2776730177 @default.
• W2951870155 hasConceptScore W2951870155C2778910044 @default.
• W2951870155 hasConceptScore W2951870155C2779515768 @default.
• W2951870155 hasConceptScore W2951870155C506065880 @default.
• W2951870155 hasIssue "33" @default.
• W2951870155 hasLocation W29518701551 @default.
• W2951870155 hasOpenAccess W2951870155 @default.
• W2951870155 hasPrimaryLocation W29518701551 @default.
• W2951870155 hasRelatedWork W1976215611 @default.
• W2951870155 hasRelatedWork W2021134057 @default.
• W2951870155 hasRelatedWork W2050436109 @default.
• W2951870155 hasRelatedWork W2092890598 @default.
• W2951870155 hasRelatedWork W2118332265 @default.
• W2951870155 hasRelatedWork W2152774028 @default.
• W2951870155 hasRelatedWork W3155189705 @default.
• W2951870155 hasRelatedWork W4206261876 @default.
• W2951870155 hasRelatedWork W4211236159 @default.
• W2951870155 hasRelatedWork W4256448539 @default.
• W2951870155 hasVolume "63" @default.
• W2951870155 isParatext "false" @default.

• next