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• W2951872022 abstract "The first total synthesis of the marine steroid alkaloid plakinamine B (1) was accomplished in seven steps starting from known aldehyde 3. Key steps in this synthesis are the attachment of a vinylpyridine side chain by an aldol reaction, a chemoselective reduction of a pyridinium salt to a vinyl tetrahydropyridine, and the introduction of the 3α-methylamino group under Mitsunobu conditions. Plakinamine B and some of its precursors with amino or pyridinium side chains show significant antimicrobial activities." @default.
• W2951872022 created "2019-06-27" @default.
• W2951872022 creator A5046572292 @default.
• W2951872022 creator A5084656439 @default.
• W2951872022 date "2014-02-01" @default.
• W2951872022 modified "2023-09-27" @default.
• W2951872022 title "First total synthesis of the marine steroid alkaloid plakinamine B" @default.
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• W2951872022 doi "https://doi.org/10.1016/j.tet.2013.11.065" @default.
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