Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951875265> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2951875265 abstract "Abstract When appropriately activated, alkali rare-earth double phosphates of the form: M3RE(PO4)2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K3RE(PO4)2 with RE = Lu, Yb, Er, Ho, Dy, Gd, Nd, Ce, plus Y and Sc – as well as the compounds: A3Lu(PO4)2, with A = Rb, and Cs. The double phosphate K3Lu(PO4)2 was reported and structurally refined previously, and it exhibited two lower-temperature phases. The compound K3Yb(PO4)2 reported here also exhibits a new second phase that occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. Comprehensive structural data and structural systematics are reported here for a number of alkali rare-earth double phosphates. Additionally, single-crystal growth methods for the preparation of large single crystals of these compounds are described, and the thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by both X-ray and neutron diffraction methods, are presented. These data represent a structural and thermal characteristics basis for continuing research on the use of alkali rare-earth double phosphates as scintillators for radiation detection – as well as for future studies of the fundamental phase properties of these compounds at elevated pressures." @default.
- W2951875265 created "2019-06-27" @default.
- W2951875265 creator A5022053925 @default.
- W2951875265 creator A5036807371 @default.
- W2951875265 creator A5045034795 @default.
- W2951875265 creator A5066083825 @default.
- W2951875265 creator A5068354127 @default.
- W2951875265 date "2016-01-01" @default.
- W2951875265 modified "2023-10-06" @default.
- W2951875265 title "ChemInform Abstract: Structural and Crystal Chemical Properties of Alkali Rare-Earth Double Phosphates." @default.
- W2951875265 cites W2203150085 @default.
- W2951875265 doi "https://doi.org/10.1002/chin.201605003" @default.
- W2951875265 hasPublicationYear "2016" @default.
- W2951875265 type Work @default.
- W2951875265 sameAs 2951875265 @default.
- W2951875265 citedByCount "2" @default.
- W2951875265 countsByYear W29518752652019 @default.
- W2951875265 countsByYear W29518752652023 @default.
- W2951875265 crossrefType "journal-article" @default.
- W2951875265 hasAuthorship W2951875265A5022053925 @default.
- W2951875265 hasAuthorship W2951875265A5036807371 @default.
- W2951875265 hasAuthorship W2951875265A5045034795 @default.
- W2951875265 hasAuthorship W2951875265A5066083825 @default.
- W2951875265 hasAuthorship W2951875265A5068354127 @default.
- W2951875265 hasConcept C115624301 @default.
- W2951875265 hasConcept C145148216 @default.
- W2951875265 hasConcept C178790620 @default.
- W2951875265 hasConcept C179104552 @default.
- W2951875265 hasConcept C185039092 @default.
- W2951875265 hasConcept C185592680 @default.
- W2951875265 hasConcept C198091228 @default.
- W2951875265 hasConcept C201770740 @default.
- W2951875265 hasConcept C62715864 @default.
- W2951875265 hasConcept C73585123 @default.
- W2951875265 hasConcept C73922627 @default.
- W2951875265 hasConcept C8010536 @default.
- W2951875265 hasConceptScore W2951875265C115624301 @default.
- W2951875265 hasConceptScore W2951875265C145148216 @default.
- W2951875265 hasConceptScore W2951875265C178790620 @default.
- W2951875265 hasConceptScore W2951875265C179104552 @default.
- W2951875265 hasConceptScore W2951875265C185039092 @default.
- W2951875265 hasConceptScore W2951875265C185592680 @default.
- W2951875265 hasConceptScore W2951875265C198091228 @default.
- W2951875265 hasConceptScore W2951875265C201770740 @default.
- W2951875265 hasConceptScore W2951875265C62715864 @default.
- W2951875265 hasConceptScore W2951875265C73585123 @default.
- W2951875265 hasConceptScore W2951875265C73922627 @default.
- W2951875265 hasConceptScore W2951875265C8010536 @default.
- W2951875265 hasLocation W29518752651 @default.
- W2951875265 hasOpenAccess W2951875265 @default.
- W2951875265 hasPrimaryLocation W29518752651 @default.
- W2951875265 hasRelatedWork W1507080831 @default.
- W2951875265 hasRelatedWork W179473328 @default.
- W2951875265 hasRelatedWork W1976930045 @default.
- W2951875265 hasRelatedWork W1980707915 @default.
- W2951875265 hasRelatedWork W1999957449 @default.
- W2951875265 hasRelatedWork W2002843064 @default.
- W2951875265 hasRelatedWork W2006451752 @default.
- W2951875265 hasRelatedWork W2014353048 @default.
- W2951875265 hasRelatedWork W2025186448 @default.
- W2951875265 hasRelatedWork W2029480780 @default.
- W2951875265 hasRelatedWork W2035727556 @default.
- W2951875265 hasRelatedWork W2052123064 @default.
- W2951875265 hasRelatedWork W2067056090 @default.
- W2951875265 hasRelatedWork W2203150085 @default.
- W2951875265 hasRelatedWork W2282450191 @default.
- W2951875265 hasRelatedWork W2521236628 @default.
- W2951875265 hasRelatedWork W2754460294 @default.
- W2951875265 hasRelatedWork W2902879290 @default.
- W2951875265 hasRelatedWork W2951681028 @default.
- W2951875265 hasRelatedWork W2969777736 @default.
- W2951875265 isParatext "false" @default.
- W2951875265 isRetracted "false" @default.
- W2951875265 magId "2951875265" @default.
- W2951875265 workType "article" @default.