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- W2951884964 abstract "The structure, stoichiometry, and chemical equilibria governing the complexes formed by lanthanide ions (Ln 3 + ) and the extractant 2-thenoyltrifluoroacetone (Htta) were studied in a biphasic system composed of aqueous 1 M NaClO 4 and the hydrophobic ionic liquid, l-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Two different Ln-tta complexes were observed in the ionic liquid phase depending on the solution conditions. A neutral Ln(tta) 3 complex predominates at low - concentration, while the anionic complex Ln(tta) 4 - is extracted into the ionic liquid phase by an anion exchange mechanism at higher tta concentrations. Both complexes have been observed in molecular solvents previously, allowing a direct and quantitative comparison of the ionic liquid based system to conventional liquid-liquid extraction systems." @default.
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- W2951884964 date "2005-01-01" @default.
- W2951884964 modified "2023-09-24" @default.
- W2951884964 title "Apples to apples : a comparison of lanthanide {beta}-diketonate complexes in molecular solvents and an ionic liquid." @default.
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