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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951892004> ?p ?o ?g. }

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• W2951892004 abstract "Rhodium-catalyzed hydroformylation of 1,5-hexadiene and 1,7-octadiene to corresponding dialdehydes was investigated in compressed CO2 and in toluene using different fluorinated phosphine compounds as ligands. A rhodium complex using tris(3,5-bis(trifluoromethyl)phenyl)phosphine is highly effective in compressed CO2 for double hydroformylation of 1,5-hexadiene, whose TOF value is much larger than those reported so far. It has been shown that this ligand is effective also for the hydroformylation of 1,7-octadiene and scCO2 is a better solvent than a conventional organic solvent of toluene for the title reaction." @default.
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• W2951892004 date "2004-02-01" @default.
• W2951892004 modified "2023-10-14" @default.
• W2951892004 title "Rhodium–tris(3,5-bis(trifluoromethyl)phenyl)phosphine catalyzed hydroformylation of dienes to dialdehydes in supercritical carbon dioxide with high activity" @default.
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• W2951892004 doi "https://doi.org/10.1016/j.tetlet.2003.10.219" @default.
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