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- W2951898607 abstract "Mesoionic compounds have proven to be valuable intermediates in organic chemistry from both physical and synthetic perspectives. These substances contain a masked 1,3-dipole within their framework and are therefore willing participants in 1,3-dipolar cycloadditions. Our interest in the chemistry of mesoionic dipoles stems from studies in our laboratory dealing with the rhodium(II)-catalyzed reactions of α-diazo carbonyl compounds in the presence of various heteroatoms. The isomunchnone class of mesoionics is easily generated from the Rh(II)-catalyzed reaction of α-diazo imides and readily undergoes cycloaddition with both electron-rich and electron-deficient dipolarophiles. This article compiles our findings in the general area of cascade reactions of isomunchnones together with relevant work from other laboratories." @default.
- W2951898607 created "2019-06-27" @default.
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- W2951898607 date "2010-08-03" @default.
- W2951898607 modified "2023-09-26" @default.
- W2951898607 title "ChemInform Abstract: Tandem Processes of Metallo Carbenoids for the Synthesis of Azapolycycles" @default.
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- W2951898607 doi "https://doi.org/10.1002/chin.199746288" @default.
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