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- W2951900529 abstract "A new ruthenium(II) complex [Ru(NO2)4(CO)(H2O)]Cl2 · 2H2O has been prepared and characterized structurally. The compound crystallizes in monoclinic space group C2 /m, with the unit cell parameters a = 12.913(2), b = 14.605(2), c = 7.4494(1)A, s =121.49(2)°; V = 1198.0(3)A3, Z = 4, Dc = 2.429 Mgm—3; μ = 1.83 mm—1; R = 0.0455, wR = 0.1552. The complex contains four neutral NO2 ligands. The ruthenium atom is six-coordinated to four nitrogen atoms of nitrogen dioxide, one carbon atom from carbon monoxide and one oxygen atom from water molecule, forming slightly distorted octahedral coordination. The preparation procedure has been discussed.Synthese und Struktur eines ungewohnlichen Carbonyl-Ruthenium(II)-Komplexes mit neutralen NO2-Liganden: [Ru(NO2)4(CO)(H2O)]Cl2·2H2OEin neuer Ruthenium(II)-Komplex, [Ru(NO2)4(CO)(H2O)]Cl2·2H2O, wurde synthetisiert und strukturell charakterisiert. Die Verbindung kristallisiert monoklin in der Raumgruppe C2/m mit den Gitterkonstanten a = 12, 913(2), b = 14, 605(2), c = 7, 4494(1)A, s = 121, 49(2)°, V = 1198, 0(3)A3, Z = 4, Dc = 2, 429 Mgm—3, μ = 1, 83 mm—1, R = 0, 0455, wR = 0, 1552. Der Komplex enthalt vier neutrale NO2-Liganden. Das Rutheniumatom ist sechsfach durch vier Stickstoffatome der Stickstoffdioxid-Molekule, das Kohlenstoffatom des Kohlenmonoxids und durch das Sauerstoffatom des Wassermolekuls koordiniert, entsprechend einer leicht verzerrten Oktaederanordnung. Der Syntheseweg wird diskutiert." @default.
- W2951900529 created "2019-06-27" @default.
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- W2951900529 date "2003-08-01" @default.
- W2951900529 modified "2023-10-14" @default.
- W2951900529 title "Synthesis and Structure of an Unusual Carbonyl Ruthenium(II) Complex Containing Neutral NO2 as Ligand: [Ru(NO2)4(CO)(H2O)]Cl2·2H2O" @default.
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- W2951900529 doi "https://doi.org/10.1002/zaac.200300147" @default.
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