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- W2951913170 abstract "Abstract Addition of traces of iridium(III) chloride with cerium(IV) sulfate (catalyst–substrate ratio (1:2994 to 1:10,000) in traditional water-bath heating resulted in the oxidation of p-chlorobenzaldehyde, p-nitrobenzaldehyde, benzyl alcohol, p-methoxy benzyl alcohol, p-xylene, and p-nitrotoluene dissolved in acetic acid to give 77%, 90%, 21.7%, 88.6%, 86.2%, and 18% yields of the products, respectively, while catechol and resorcinol polymerized. Oxidation of aldehydes and alcohols resulted as usual in the corresponding acids and aldehydes, respectively, while p-xylene and p-nitrotoluene gave p-tolualdehyde and p-nitrobenzoic acid. Conditions were obtained for getting the highest yields under the experimental conditions." @default.
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- W2951913170 date "2009-10-27" @default.
- W2951913170 modified "2023-09-23" @default.
- W2951913170 title "ChemInform Abstract: Liquid-Phase Oxidation of Some Aromatic Aldehydes, Hydrocarbons, and Alcohols by Cerium(IV) Catalyzed by Iridium(III) in Acidic Medium." @default.
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- W2951913170 doi "https://doi.org/10.1002/chin.200943033" @default.
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