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- W2951927891 abstract "Abstract The stereochemical course of the 1,2-addition upon treatment of various 1-thio-4-oxo sugars with McMgXand McLi has been determined. The effects of reagent, solvent, and neighboring functionalities in the gluco/galacto (non-chelation/chelation controlled) product distribution are detailed. Stereocontrolled 1,2-addition to these 4-oxo sugars provide access to a number of differently functionalized F unit building blocks of the moenomycin family, and demonstrate the versatility of this transformation." @default.
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- W2951927891 date "1999-06-01" @default.
- W2951927891 modified "2023-10-16" @default.
- W2951927891 title "Diastereofacial selection in the 1,2-addition of MeMgX and McLi to 4-oxo sugar:Efficient synthesis of 4-C-methyl-l-S-β-D-gluco- and galactopyranoside building blocks of moenomycin" @default.
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- W2951927891 doi "https://doi.org/10.1016/s0040-4039(99)00823-0" @default.
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