Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951950412> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2951950412 abstract "Some homogeneous transition metal catalysts are highly active to cleave σ-bonds between group 14 elements under mild reaction conditions. Various unsaturated compounds insert into the a-bonds to afford a wide variety of products having the group 14 elements. We have utilized silylstannanes (Si-Sn), disilanes (Si-Si), and distannanes (Sn-Sn) in the presence of a transition metal catalyst to realize 1, 4-silylstannation of 1, 3-dienes, 1, 2-silylstannation of olefins, dimerization and bis-silylation of 1, 3-dienes, 1, 4-carbosilylation of 1, 3-dienes, silylation of allylic esters, and bisstannylation of 1, 3-dienes. The structures and fluxional behavior of cis-bis (stannyl) bis (phosphine) platinum, cis-bis (silyl) bis (phosphine) platinum, and cis-bis (stannyl) bis (phosphine) palladium complexes were examined. In the fluxional process, all the spin-spin couplings are retained. The fluxionality is attributed to unimolecular twist-rotation via a pseudotetrahedral transition state." @default.
- W2951950412 created "2019-06-27" @default.
- W2951950412 creator A5065148586 @default.
- W2951950412 creator A5084976321 @default.
- W2951950412 date "2000-01-01" @default.
- W2951950412 modified "2023-09-29" @default.
- W2951950412 title "Transition Metal Catalysis Involving Cleavages of .SIGMA.-Bonds between Group 14 Elements and Characterization of Metal Complexes Relevant to the Catalyst Intermediates." @default.
- W2951950412 cites W1970006586 @default.
- W2951950412 cites W2034745057 @default.
- W2951950412 cites W2155343971 @default.
- W2951950412 cites W2772078650 @default.
- W2951950412 doi "https://doi.org/10.5059/yukigoseikyokaishi.58.199" @default.
- W2951950412 hasPublicationYear "2000" @default.
- W2951950412 type Work @default.
- W2951950412 sameAs 2951950412 @default.
- W2951950412 citedByCount "1" @default.
- W2951950412 crossrefType "journal-article" @default.
- W2951950412 hasAuthorship W2951950412A5065148586 @default.
- W2951950412 hasAuthorship W2951950412A5084976321 @default.
- W2951950412 hasBestOaLocation W29519504121 @default.
- W2951950412 hasConcept C106773901 @default.
- W2951950412 hasConcept C120095180 @default.
- W2951950412 hasConcept C155647269 @default.
- W2951950412 hasConcept C161790260 @default.
- W2951950412 hasConcept C178790620 @default.
- W2951950412 hasConcept C185592680 @default.
- W2951950412 hasConcept C188027245 @default.
- W2951950412 hasConcept C2777716191 @default.
- W2951950412 hasConcept C502130503 @default.
- W2951950412 hasConcept C518104683 @default.
- W2951950412 hasConcept C5304478 @default.
- W2951950412 hasConcept C544153396 @default.
- W2951950412 hasConcept C71240020 @default.
- W2951950412 hasConceptScore W2951950412C106773901 @default.
- W2951950412 hasConceptScore W2951950412C120095180 @default.
- W2951950412 hasConceptScore W2951950412C155647269 @default.
- W2951950412 hasConceptScore W2951950412C161790260 @default.
- W2951950412 hasConceptScore W2951950412C178790620 @default.
- W2951950412 hasConceptScore W2951950412C185592680 @default.
- W2951950412 hasConceptScore W2951950412C188027245 @default.
- W2951950412 hasConceptScore W2951950412C2777716191 @default.
- W2951950412 hasConceptScore W2951950412C502130503 @default.
- W2951950412 hasConceptScore W2951950412C518104683 @default.
- W2951950412 hasConceptScore W2951950412C5304478 @default.
- W2951950412 hasConceptScore W2951950412C544153396 @default.
- W2951950412 hasConceptScore W2951950412C71240020 @default.
- W2951950412 hasLocation W29519504121 @default.
- W2951950412 hasOpenAccess W2951950412 @default.
- W2951950412 hasPrimaryLocation W29519504121 @default.
- W2951950412 hasRelatedWork W100735277 @default.
- W2951950412 hasRelatedWork W104010375 @default.
- W2951950412 hasRelatedWork W1972514222 @default.
- W2951950412 hasRelatedWork W2024688937 @default.
- W2951950412 hasRelatedWork W2029224795 @default.
- W2951950412 hasRelatedWork W2034194789 @default.
- W2951950412 hasRelatedWork W2062176372 @default.
- W2951950412 hasRelatedWork W2103958276 @default.
- W2951950412 hasRelatedWork W2128305374 @default.
- W2951950412 hasRelatedWork W2131895443 @default.
- W2951950412 hasRelatedWork W2139405736 @default.
- W2951950412 hasRelatedWork W2328853935 @default.
- W2951950412 hasRelatedWork W2949749109 @default.
- W2951950412 hasRelatedWork W2950115013 @default.
- W2951950412 hasRelatedWork W2952585760 @default.
- W2951950412 hasRelatedWork W3028095953 @default.
- W2951950412 hasRelatedWork W3095211415 @default.
- W2951950412 hasRelatedWork W3212885287 @default.
- W2951950412 hasRelatedWork W592408894 @default.
- W2951950412 hasRelatedWork W2870935660 @default.
- W2951950412 isParatext "false" @default.
- W2951950412 isRetracted "false" @default.
- W2951950412 magId "2951950412" @default.
- W2951950412 workType "article" @default.