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- W2951956315 abstract "[reaction: see text] Rh-Me-BDPMI (1a) complex can be an effective catalyst for the hydrogenations of (E)- and (Z)-beta-(acylamino)acrylates, in which the Z-isomers hydrogenated with the same or even higher ee values than the corresponding E-isomers. The conversion yield and enantioselectivity of E- and Z-isomers were largely dependent on the solvent, and thus, the E-isomers were hydrogenated more effectively in CH(2)Cl(2), whereas the Z-isomers were hydrogenated more effectively in polar MeOH solvent." @default.
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- W2951956315 date "2002-06-19" @default.
- W2951956315 modified "2023-09-27" @default.
- W2951956315 title "Rh(I)-Catalyzed Enantioselective Hydrogenation of (<i>E</i>)- and (<i>Z</i>)-β-(Acylamino)acrylates Using 1,4-Bisphosphine Ligands under Mild Conditions" @default.
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- W2951956315 doi "https://doi.org/10.1021/ol0261884" @default.
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