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- W295196503 abstract "The nondialyzable melanoidin prepared from glucose-ammonia system (kept in pH 5.3~6.0 during the reaction) was hydrolyzed. The hydrolyzate was fractionated by DEAE-cellulose column and Dowex 50 W column. Deoxyfructosazine and its 6-isomer were respectively isolated from main two fractions, and identified. Even on boiling the melanoidin in aqueous solution, these pyrazines as well as imidazoles and β-hydroxy pyridines in the melanoidin were liberated.Furthermore, amounts of these heterocyclic compounds liberated from the nondialyzable melanoidin and the fractionated melanoidins (fractionated into five fractions on DEAE-cellulose column according to the method described previously) were examined.The results obtained seem to suggest that these heterocyclic compounds are not present probably as a molecular skelton or an inclusion compound in the melanoidin, but as a small moiety of the melanoidin molecule with loose chemical bond." @default.
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- W295196503 date "1975-01-01" @default.
- W295196503 modified "2023-10-18" @default.
- W295196503 title "Melanoidin produced from the reaction of glucose and ammonia. IV. Isolation of deoxyfructosazine and its 6-isomer from the nondialyzable melanoidin hydrolyzate." @default.
- W295196503 doi "https://doi.org/10.1271/bbb1961.39.1143" @default.
- W295196503 hasPublicationYear "1975" @default.
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