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- W2951982008 abstract "In this study, fluorine-containing pentasubstituted pyridine derivatives 9a−m were prepared regioselectively in good yields by the intermolecular cyclization of a variety of N-silyl-1-azaallylic anion intermediates 7, which were generated from a functionalized silane 5 and an aromatic/aliphatic nitrile 6 with perfluoroalkene 8. Also, 7-fluoro-8-(trifluoromethyl)-1H-1,6-naphthyridin-4-one derivatives 11a−k were synthesized in excellent yields by the subsequent base-promoted intramolecular skeletal transformation of the resulting pyridine derivatives 10a−k." @default.
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- W2951982008 date "2007-06-28" @default.
- W2951982008 modified "2023-10-16" @default.
- W2951982008 title "Novel Synthesis of 7-Fluoro-8-(trifluoromethyl)- 1<i>H</i>-1,6-naphthyridin-4-one Derivatives: Intermolecular Cyclization of an <i>N</i>-Silyl-1-azaallyl Anion with Perfluoroalkene and Subsequent Intramolecular Skeletal Transformation of the Resulting Pentasubstituted Pyridines" @default.
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- W2951982008 doi "https://doi.org/10.1021/jo070564m" @default.
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