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- W2951982487 abstract "The debromination of α-bromoketones with an easily accessible ionic liquid, 1-methyl-3-pentylimidazolium tetrafluoroborate, [pmIm]BF4 under microwave irradiation has been investigated. By controlling the reaction time gem-α-dibromoketones are selectively debrominated to either monobromo or debromoketones. The α-monobromo- and α-monoiodoketones are dehalogenated while the corresponding chloroketones remain inert. The activated vic-bromoacetates are converted to the corresponding (E)-alkenes by the same procedure. These reactions do not require any organic solvent, any metal or any conventional reducing agent. The ionic liquid works here as catalyst as well as reaction medium and is recycled without any appreciable loss of its catalytic efficiency." @default.
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- W2951982487 date "2007-01-01" @default.
- W2951982487 modified "2023-09-28" @default.
- W2951982487 title "Ionic liquid promoted selective debromination of α-bromoketones under microwave irradiation" @default.
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- W2951982487 doi "https://doi.org/10.1016/j.tet.2006.10.035" @default.
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