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• W2951983670 abstract "We found a very efficient one-pot phosphination reaction starting with Ph3P, which by reaction with Na metal in liquid ammonia gives Ph2P− ions that reacted with R3SnCl to afford (trialkylstannyl)diphenylphosphine. The palladium-catalyzed coupling reaction of these stannanes with aryl iodides yield functionalized phosphines in high yield (69–97%). The use of Ph3P as starting reagent, the endurance of the reaction to a wide variety of functional groups and the easiness of a one-pot reaction make this method a useful and versatile approach to tertiary phosphine oxides." @default.
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• W2951983670 date "2002-12-01" @default.
• W2951983670 modified "2023-10-17" @default.
• W2951983670 title "One-pot palladium-catalyzed phosphination of aryl iodides with Ph2PSnR3" @default.
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• W2951983670 doi "https://doi.org/10.1016/s0022-328x(02)02014-4" @default.
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