Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952003558> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2952003558 endingPage "4240" @default.
- W2952003558 startingPage "4234" @default.
- W2952003558 abstract "The crystal structure of the S = 1/2 kagome system Cs2ZrCu3F12 has been determined at both 295 and 125 K via single-crystal X-ray diffraction. A first-order structural phase transition is seen near 225 K, confirmed by variable-temperature synchrotron powder diffraction studies, in which the structure transforms from rhombohedral (R3m) to monoclinic (P21/m). A corresponding abrupt change in dielectric constant is observed near the same temperature. The phase transition is driven by a dramatic change in coordination around the Zr site, which changes from regular octahedral in the rhombohedral phase to a seven-coordinate environment in the monoclinic phase. This leads to a severe buckling of the copper fluoride kagome layers and significant changes in the geometry around the Cu sites, which correlates with both the observed dielectric anomaly and a previously observed anomaly in magnetic susceptibility. It is suggested that this structural phase transition ultimately permits long-range antiferromagnetic ord..." @default.
- W2952003558 created "2019-06-27" @default.
- W2952003558 creator A5008307484 @default.
- W2952003558 creator A5034834722 @default.
- W2952003558 creator A5047581894 @default.
- W2952003558 creator A5087618485 @default.
- W2952003558 creator A5091879518 @default.
- W2952003558 date "2011-09-02" @default.
- W2952003558 modified "2023-09-24" @default.
- W2952003558 title "Structural Phase Transition in the S = 1/2 Kagome System Cs2ZrCu3F12 and a Comparison to the Valence-Bond-Solid Phase in Rb2SnCu3F12" @default.
- W2952003558 cites W1535145633 @default.
- W2952003558 cites W1993853764 @default.
- W2952003558 cites W1995374132 @default.
- W2952003558 cites W1996551885 @default.
- W2952003558 cites W2005073755 @default.
- W2952003558 cites W2008102521 @default.
- W2952003558 cites W2017629546 @default.
- W2952003558 cites W2020249673 @default.
- W2952003558 cites W2025591766 @default.
- W2952003558 cites W2045033024 @default.
- W2952003558 cites W2050435665 @default.
- W2952003558 cites W2087041232 @default.
- W2952003558 cites W2090025488 @default.
- W2952003558 cites W2091393784 @default.
- W2952003558 cites W2101741054 @default.
- W2952003558 cites W2131097405 @default.
- W2952003558 cites W2131350133 @default.
- W2952003558 cites W2165530487 @default.
- W2952003558 cites W2242459406 @default.
- W2952003558 cites W3122582007 @default.
- W2952003558 doi "https://doi.org/10.1021/cm201762f" @default.
- W2952003558 hasPublicationYear "2011" @default.
- W2952003558 type Work @default.
- W2952003558 sameAs 2952003558 @default.
- W2952003558 citedByCount "18" @default.
- W2952003558 countsByYear W29520035582013 @default.
- W2952003558 countsByYear W29520035582014 @default.
- W2952003558 countsByYear W29520035582015 @default.
- W2952003558 countsByYear W29520035582018 @default.
- W2952003558 countsByYear W29520035582019 @default.
- W2952003558 countsByYear W29520035582020 @default.
- W2952003558 countsByYear W29520035582021 @default.
- W2952003558 countsByYear W29520035582022 @default.
- W2952003558 crossrefType "journal-article" @default.
- W2952003558 hasAuthorship W2952003558A5008307484 @default.
- W2952003558 hasAuthorship W2952003558A5034834722 @default.
- W2952003558 hasAuthorship W2952003558A5047581894 @default.
- W2952003558 hasAuthorship W2952003558A5087618485 @default.
- W2952003558 hasAuthorship W2952003558A5091879518 @default.
- W2952003558 hasConcept C121332964 @default.
- W2952003558 hasConcept C139358910 @default.
- W2952003558 hasConcept C149288129 @default.
- W2952003558 hasConcept C168900304 @default.
- W2952003558 hasConcept C178429038 @default.
- W2952003558 hasConcept C178790620 @default.
- W2952003558 hasConcept C185592680 @default.
- W2952003558 hasConcept C192562407 @default.
- W2952003558 hasConcept C26873012 @default.
- W2952003558 hasConcept C32909587 @default.
- W2952003558 hasConcept C44280652 @default.
- W2952003558 hasConcept C8010536 @default.
- W2952003558 hasConceptScore W2952003558C121332964 @default.
- W2952003558 hasConceptScore W2952003558C139358910 @default.
- W2952003558 hasConceptScore W2952003558C149288129 @default.
- W2952003558 hasConceptScore W2952003558C168900304 @default.
- W2952003558 hasConceptScore W2952003558C178429038 @default.
- W2952003558 hasConceptScore W2952003558C178790620 @default.
- W2952003558 hasConceptScore W2952003558C185592680 @default.
- W2952003558 hasConceptScore W2952003558C192562407 @default.
- W2952003558 hasConceptScore W2952003558C26873012 @default.
- W2952003558 hasConceptScore W2952003558C32909587 @default.
- W2952003558 hasConceptScore W2952003558C44280652 @default.
- W2952003558 hasConceptScore W2952003558C8010536 @default.
- W2952003558 hasIssue "18" @default.
- W2952003558 hasLocation W29520035581 @default.
- W2952003558 hasOpenAccess W2952003558 @default.
- W2952003558 hasPrimaryLocation W29520035581 @default.
- W2952003558 hasRelatedWork W1362500 @default.
- W2952003558 hasRelatedWork W1965515165 @default.
- W2952003558 hasRelatedWork W1965652764 @default.
- W2952003558 hasRelatedWork W1966327879 @default.
- W2952003558 hasRelatedWork W1982393774 @default.
- W2952003558 hasRelatedWork W1983485715 @default.
- W2952003558 hasRelatedWork W2062309494 @default.
- W2952003558 hasRelatedWork W2067828265 @default.
- W2952003558 hasRelatedWork W2740654917 @default.
- W2952003558 hasRelatedWork W2899084033 @default.
- W2952003558 hasVolume "23" @default.
- W2952003558 isParatext "false" @default.
- W2952003558 isRetracted "false" @default.
- W2952003558 magId "2952003558" @default.
- W2952003558 workType "article" @default.