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- W2952007655 abstract "Ionic liquids, that is molten salts, may represent activating and stabilizing solvents for C–C coupling reactions. In particular, tetrabutylammonium bromide (TBAB) is particularly suitable for Heck reactions as it enhances reaction rates. In the presence of tetrabutylammonium acetate as base, palladium complex with benzothiazolidene as ligands as well palladium acetate are transformed to Pd-nanoparticles which allow regio- and stereo-specific Heck reactions with very high TON and TOF. Beside this, TBAB enhances, by solvation, the formation and reactivity of carbanions. A comparative study on effects exerted by different ionic liquids on catalyst stabilization, reaction rates and regio- and stereo-selectivity in the C–C coupling reactions is also reported." @default.
- W2952007655 created "2019-06-27" @default.
- W2952007655 creator A5035070776 @default.
- W2952007655 date "2004-05-18" @default.
- W2952007655 modified "2023-10-16" @default.
- W2952007655 title "Regio- and stereo-selective carbon–carbon bond formation in ionic liquids" @default.
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- W2952007655 doi "https://doi.org/10.1016/j.molcata.2003.12.028" @default.
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