Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952009166> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2952009166 abstract "Transition metal−benzyne complexes have found many applications in organic synthesis, mechanistic studies, and the synthesis of functional materials. In sharp contrast, the chemistry of transition metal−carboryne complexes, especially late transition metal complexes, is virtually unknown. This communication reports a novel nickel-mediated regioselective [2 + 2 + 2] cycloaddition reaction of carboryne with alkynes via the Ni−carboryne intermediate (η2-C2B10H10)Ni(PPh3)2. Because of the bulkiness of the carborane moiety, a high regioselectivity was achieved in the reactions involving unsymmetrical alkynes. This work furnishes a novel method for the preparation of highly substituted benzocarboranes which are difficult to obtain by other methods." @default.
- W2952009166 created "2019-06-27" @default.
- W2952009166 creator A5020235406 @default.
- W2952009166 creator A5030076543 @default.
- W2952009166 creator A5078892060 @default.
- W2952009166 date "2010-09-23" @default.
- W2952009166 modified "2023-09-27" @default.
- W2952009166 title "ChemInform Abstract: Nickel-Catalyzed Regioselective [2 + 2 + 2] Cycloaddition of Carboryne with Alkynes." @default.
- W2952009166 cites W2128501905 @default.
- W2952009166 doi "https://doi.org/10.1002/chin.201042175" @default.
- W2952009166 hasPublicationYear "2010" @default.
- W2952009166 type Work @default.
- W2952009166 sameAs 2952009166 @default.
- W2952009166 citedByCount "0" @default.
- W2952009166 crossrefType "journal-article" @default.
- W2952009166 hasAuthorship W2952009166A5020235406 @default.
- W2952009166 hasAuthorship W2952009166A5030076543 @default.
- W2952009166 hasAuthorship W2952009166A5078892060 @default.
- W2952009166 hasConcept C106773901 @default.
- W2952009166 hasConcept C161790260 @default.
- W2952009166 hasConcept C171811041 @default.
- W2952009166 hasConcept C178790620 @default.
- W2952009166 hasConcept C185592680 @default.
- W2952009166 hasConcept C21951064 @default.
- W2952009166 hasConcept C2776568683 @default.
- W2952009166 hasConcept C2779664164 @default.
- W2952009166 hasConcept C504270822 @default.
- W2952009166 hasConcept C59759590 @default.
- W2952009166 hasConceptScore W2952009166C106773901 @default.
- W2952009166 hasConceptScore W2952009166C161790260 @default.
- W2952009166 hasConceptScore W2952009166C171811041 @default.
- W2952009166 hasConceptScore W2952009166C178790620 @default.
- W2952009166 hasConceptScore W2952009166C185592680 @default.
- W2952009166 hasConceptScore W2952009166C21951064 @default.
- W2952009166 hasConceptScore W2952009166C2776568683 @default.
- W2952009166 hasConceptScore W2952009166C2779664164 @default.
- W2952009166 hasConceptScore W2952009166C504270822 @default.
- W2952009166 hasConceptScore W2952009166C59759590 @default.
- W2952009166 hasLocation W29520091661 @default.
- W2952009166 hasOpenAccess W2952009166 @default.
- W2952009166 hasPrimaryLocation W29520091661 @default.
- W2952009166 hasRelatedWork W1526526404 @default.
- W2952009166 hasRelatedWork W1966751524 @default.
- W2952009166 hasRelatedWork W1967577007 @default.
- W2952009166 hasRelatedWork W1967897724 @default.
- W2952009166 hasRelatedWork W2025827756 @default.
- W2952009166 hasRelatedWork W2057112908 @default.
- W2952009166 hasRelatedWork W2063189391 @default.
- W2952009166 hasRelatedWork W2070313020 @default.
- W2952009166 hasRelatedWork W2084944709 @default.
- W2952009166 hasRelatedWork W2087462883 @default.
- W2952009166 hasRelatedWork W2128501905 @default.
- W2952009166 hasRelatedWork W2950154525 @default.
- W2952009166 hasRelatedWork W2950562027 @default.
- W2952009166 hasRelatedWork W2950705574 @default.
- W2952009166 hasRelatedWork W2950935744 @default.
- W2952009166 hasRelatedWork W2952370911 @default.
- W2952009166 hasRelatedWork W2952669126 @default.
- W2952009166 hasRelatedWork W2952782456 @default.
- W2952009166 hasRelatedWork W3017277934 @default.
- W2952009166 hasRelatedWork W3127552264 @default.
- W2952009166 isParatext "false" @default.
- W2952009166 isRetracted "false" @default.
- W2952009166 magId "2952009166" @default.
- W2952009166 workType "article" @default.