Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952015734> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2952015734 abstract "Cobalt salts exert an unexpected and profound influence on the reactivity of epoxides with dimethylsulfoxonium methylide. In the presence of a cobalt catalyst, conditions for epoxide to an oxetane ring expansion instead deliver homoallylic alcohol products, corresponding to a two-carbon epoxide homologation/ring-opening tandem process. The observed reactivity change appears to be specifically due to cobalt salts and is broadly applicable to a variety of epoxides, retaining the initial stereochemistry. This transformation also provides operationally simple access to enantiopure homoallylic alcohols from chiral epoxides without use of organometallic reagents. Tandem epoxidation–homologation of aldehydes in a single step is also demonstrated." @default.
- W2952015734 created "2019-06-27" @default.
- W2952015734 creator A5009946089 @default.
- W2952015734 creator A5032637871 @default.
- W2952015734 creator A5043992105 @default.
- W2952015734 creator A5090938606 @default.
- W2952015734 date "2016-06-01" @default.
- W2952015734 modified "2023-09-27" @default.
- W2952015734 title "ChemInform Abstract: Divergent Reactivity via Cobalt Catalysis: An Epoxide Olefination." @default.
- W2952015734 cites W2369382276 @default.
- W2952015734 doi "https://doi.org/10.1002/chin.201625033" @default.
- W2952015734 hasPublicationYear "2016" @default.
- W2952015734 type Work @default.
- W2952015734 sameAs 2952015734 @default.
- W2952015734 citedByCount "0" @default.
- W2952015734 crossrefType "journal-article" @default.
- W2952015734 hasAuthorship W2952015734A5009946089 @default.
- W2952015734 hasAuthorship W2952015734A5032637871 @default.
- W2952015734 hasAuthorship W2952015734A5043992105 @default.
- W2952015734 hasAuthorship W2952015734A5090938606 @default.
- W2952015734 hasConcept C142724271 @default.
- W2952015734 hasConcept C146686406 @default.
- W2952015734 hasConcept C159985019 @default.
- W2952015734 hasConcept C161790260 @default.
- W2952015734 hasConcept C178790620 @default.
- W2952015734 hasConcept C185592680 @default.
- W2952015734 hasConcept C192562407 @default.
- W2952015734 hasConcept C204787440 @default.
- W2952015734 hasConcept C21951064 @default.
- W2952015734 hasConcept C2776910235 @default.
- W2952015734 hasConcept C2776920199 @default.
- W2952015734 hasConcept C2777052750 @default.
- W2952015734 hasConcept C2777814067 @default.
- W2952015734 hasConcept C2780378348 @default.
- W2952015734 hasConcept C2780497619 @default.
- W2952015734 hasConcept C40875361 @default.
- W2952015734 hasConcept C515602321 @default.
- W2952015734 hasConcept C71924100 @default.
- W2952015734 hasConcept C93237805 @default.
- W2952015734 hasConceptScore W2952015734C142724271 @default.
- W2952015734 hasConceptScore W2952015734C146686406 @default.
- W2952015734 hasConceptScore W2952015734C159985019 @default.
- W2952015734 hasConceptScore W2952015734C161790260 @default.
- W2952015734 hasConceptScore W2952015734C178790620 @default.
- W2952015734 hasConceptScore W2952015734C185592680 @default.
- W2952015734 hasConceptScore W2952015734C192562407 @default.
- W2952015734 hasConceptScore W2952015734C204787440 @default.
- W2952015734 hasConceptScore W2952015734C21951064 @default.
- W2952015734 hasConceptScore W2952015734C2776910235 @default.
- W2952015734 hasConceptScore W2952015734C2776920199 @default.
- W2952015734 hasConceptScore W2952015734C2777052750 @default.
- W2952015734 hasConceptScore W2952015734C2777814067 @default.
- W2952015734 hasConceptScore W2952015734C2780378348 @default.
- W2952015734 hasConceptScore W2952015734C2780497619 @default.
- W2952015734 hasConceptScore W2952015734C40875361 @default.
- W2952015734 hasConceptScore W2952015734C515602321 @default.
- W2952015734 hasConceptScore W2952015734C71924100 @default.
- W2952015734 hasConceptScore W2952015734C93237805 @default.
- W2952015734 hasLocation W29520157341 @default.
- W2952015734 hasOpenAccess W2952015734 @default.
- W2952015734 hasPrimaryLocation W29520157341 @default.
- W2952015734 hasRelatedWork W1480577207 @default.
- W2952015734 hasRelatedWork W1826212367 @default.
- W2952015734 hasRelatedWork W2018206021 @default.
- W2952015734 hasRelatedWork W2033308962 @default.
- W2952015734 hasRelatedWork W2050605509 @default.
- W2952015734 hasRelatedWork W2091299361 @default.
- W2952015734 hasRelatedWork W2126837996 @default.
- W2952015734 hasRelatedWork W2155316012 @default.
- W2952015734 hasRelatedWork W2319736866 @default.
- W2952015734 hasRelatedWork W2524370388 @default.
- W2952015734 hasRelatedWork W2613778660 @default.
- W2952015734 hasRelatedWork W2949248362 @default.
- W2952015734 hasRelatedWork W2950437805 @default.
- W2952015734 hasRelatedWork W2950590415 @default.
- W2952015734 hasRelatedWork W2951126438 @default.
- W2952015734 hasRelatedWork W2951506828 @default.
- W2952015734 hasRelatedWork W2951577001 @default.
- W2952015734 hasRelatedWork W2953295562 @default.
- W2952015734 hasRelatedWork W3165182630 @default.
- W2952015734 hasRelatedWork W1963807479 @default.
- W2952015734 isParatext "false" @default.
- W2952015734 isRetracted "false" @default.
- W2952015734 magId "2952015734" @default.
- W2952015734 workType "article" @default.