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- W2952018977 abstract "In moist air or by contact with water during washing, KOs2O6 absorbs water molecules into the structure to produce KOs2O6·nH2O, 0 < n < 0.1. This water is reversibly lost on heating above ∼430 K in flowing or static gas environments. Variable temperature powder neutron and X-ray diffraction show that an increase in lattice parameter occurs when water enters the pyrochlore structure and the water molecules are located in the α cages displacing a portion of the potassium ions to adjacent sites. On removing water the lattice parameter and structure revert to those of the normal β-pyrochlore crystallographic description. Hydration has the effect of reducing the onset of superconducting behavior from a critical temperature of 10.25 K in fully dry KOs2O6 to 9.75 K in KOs2O6·0.1H2O." @default.
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- W2952018977 date "2008-05-13" @default.
- W2952018977 modified "2023-09-24" @default.
- W2952018977 title "ChemInform Abstract: Hydration, Structure, and Superconductivity of KOs2O6×nH2O." @default.
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- W2952018977 doi "https://doi.org/10.1002/chin.200820011" @default.
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