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- W2952019957 abstract "Dimethyl-4,5-bis(bromomethylene)furan-2,3-dioate 2, generated “in situ” from the tetrabromo compound 1 and sodium iodide, was condensed with unsymmetrical quinones 7c-e, 10 and the 2-or 3-bromo naphthoquinones 8 or 9. Starting from the latter, the cycloadditions were found more regioselective than from the non brominated quinones. Assignment of the regioisomers was made by 2D 1H-13C HMQC and HMBC techniques performed on 12d, 11e and 12e. Calculations of HOMO and LUMO energies and the orbital coefficients by the semiempirical AM1 method indicate that 2 can be characterized as a rather neutral non polarised diene." @default.
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- W2952019957 date "1995-08-01" @default.
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- W2952019957 title "Cycloaddition of a furan analogue of o-quinodimethane with quinones and their bromo derivatives" @default.
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- W2952019957 doi "https://doi.org/10.1016/0040-4020(95)00534-f" @default.
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