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- W2952045368 abstract "The development of a highly enantioselective catalytic oxa-Pictet–Spengler reaction has proven a great challenge for chemical synthesis. We now report the first example of such a process, which was realized by utilizing a nitrated confined imidodiphosphoric acid catalyst. Our approach provides substituted isochroman derivatives from both aliphatic and aromatic aldehydes with high yields and excellent enantioselectivities. DFT calculations provide insight into the reaction mechanism." @default.
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- W2952045368 date "2016-12-01" @default.
- W2952045368 modified "2023-10-02" @default.
- W2952045368 title "ChemInform Abstract: Nitrated Confined Imidodiphosphates Enable a Catalytic Asymmetric Oxa-Pictet-Spengler Reaction." @default.
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- W2952045368 doi "https://doi.org/10.1002/chin.201652281" @default.
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