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- W2952046863 abstract "The development of catalytic asymmetric carbon–carbon bond-forming reactions of alkylnitriles that do not have an activating group at the α-position, under proton-transfer conditions, is a challenging research topic. Here, we report catalytic asymmetric direct-type 1,4-addition reactions of alkylnitriles with α,β-unsaturated amides by using a catalytic amount of potassium hexamethyldisilazide (KHMDS) with a chiral macro crown ether. The desired reactions proceeded in high yields with good diastereo- and enantioselectivities. To our knowledge, this is the first example of catalytic asymmetric direct-type 1,4-addition reaction of alkylnitriles without any activating group at the α-position." @default.
- W2952046863 created "2019-06-27" @default.
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- W2952046863 date "2016-01-01" @default.
- W2952046863 modified "2023-10-16" @default.
- W2952046863 title "ChemInform Abstract: Catalytic Asymmetric 1,4-Addition Reactions of Simple Alkylnitriles." @default.
- W2952046863 cites W1804907305 @default.
- W2952046863 doi "https://doi.org/10.1002/chin.201606030" @default.
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