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- W2952049744 abstract "In the presence of cuprous iodide, the palladium catalyzed coupling reaction of substituted tetrafluorophenyl halides with 1- alkynes gives the corresponding fluoroaryl alkynes in good to excellent yields under mild conditions. Both 4-substituted (methoxy, N,N-dimethylamino, morpholino) tetrafluorophenyl iodides and bromides work well, and alkyl, trimethylsilyl, phenyl, hydroxy, and ether functionalities in the alkyne moiety are tolerated under the reaction conditions. This methodology provides a practical synthesis of substituted fluorinated aryl alkynes." @default.
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- W2952049744 date "1990-11-01" @default.
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- W2952049744 title "Palladium/Cuprous Iodide Catalyzed Coupling of Substituted Tetrafluorophenyl Halides With 1-Alkynes" @default.
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- W2952049744 doi "https://doi.org/10.1016/s0022-1139(00)80502-3" @default.
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