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• W2952052223 abstract "The radical anions from thiobenzophenone, thiobenzoyltriphenylsilane, and 3,5-di-tert-butylthiobenzoyltriphenylsilane were detected by EPR spectroscopy when these compounds were reacted with a number of Grignard reagents, RMgBr. The radical adducts resulting from addition of R• radicals to the thiones were also detected. The formation of the radical anions indicates unambiguously the occurrence of a SET process which might be the initial stage of these reactions. In the case of tris(trimethylsilyl)ethanethial only the radical adducts were detected. The first reduction potentials of these thiones have also been measured in order to verify the feasibility of the SET process. In agreement with the EPR experiments, the calculated standard free energy changes suggest that electron transfer is possible in the first three cases and disfavored with the thioaldehyde." @default.
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• W2952052223 date "1997-09-01" @default.
• W2952052223 modified "2023-09-26" @default.
• W2952052223 title "Reactions between Grignard Reagents and Thiocarbonyl Compounds: A Revisitation" @default.
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• W2952052223 doi "https://doi.org/10.1021/jo9708001" @default.
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