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- W2952052585 abstract "Claims that cis-bis(2,2′-bipyridine)bis(pyridine)ruthenium(II) salts, cis-[Ru(bipy)2(py)2]X2, form covalent hydrates when treated with hydroxide ion are shown to be in error. Previously reported n.m.r. data are shown to have been incorrectly interpreted, and a full analysis of the two-dimensional 1H n.m.r. spectra of the complex cation is presented. The crystal structure of the double salt cis-[Ru(bipy)2(py)2][BF4]2·0.5[Hpy][BF4][space group P, a= 1.018 8(2), b= 1.219 7(2), c= 1.559 2(2) nm, α= 70.82(2), β= 73.74(2), γ= 72.14(2)°, and Z= 2; R= 0.12 for 1 380 independent reflections with |F2| > σ(F2)] reveals all the N-heterocyclic rings to be conventionally aromatic." @default.
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- W2952052585 date "1988-10-25" @default.
- W2952052585 modified "2023-09-25" @default.
- W2952052585 title "ChemInform Abstract: cis-Bis(2,2′-bipyridine)bis(pyridine)ruthenium(II) Salts: A Spectroscopic and Structural Study." @default.
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- W2952052585 doi "https://doi.org/10.1002/chin.198843057" @default.
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