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- W2952059144 abstract "Abstract A method of stepwise chemical degradation was elaborated on a μg quantity of 3-O-α- l -fucosyllactose. The key step, TiCl4-catalysed dithioacetal formation from the permethylated N-4-nitrophenyl triosylamine (4) was accompanied by quantitative defucosylation. [14C]Acetylation of the dried mercaptalation mixture gave radiolabelled 3,5-di-O-[14C]acetyl-4-O-(2,3,4,6-tetra-O-methyl-β - d -galactopyranosyl)-2,6-di-O-methyl- d -glucose diethyl dithioacetal (7) and 5-O-[14C]acetyl-2,3,4-tri-O-methyl- l -fucose diethyl dithioacetal (8). The former was further degraded via the bis(sulfone), and thereby 2,3,4,6-tetra-O-methyl- d -galactose (13) was expelled. The monosaccharide branches, fucose and galactose, were identified as derivatives 8 and 13, respectively, by comparison with authentic samples. Isolation of microquantities of products was carried out by preparative TLC." @default.
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- W2952059144 date "1995-04-18" @default.
- W2952059144 modified "2023-09-27" @default.
- W2952059144 title "ChemInform Abstract: Selective Defucosylation by Mercaptolysis. A Potential Step in Analyzing Branched Oligosaccharides." @default.
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- W2952059144 doi "https://doi.org/10.1002/chin.199516257" @default.
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