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- W2952063743 abstract "We report the first examples of straightforward trans-hydroboration of internal alkynes at room temperature with 9-BBN, producing five-membered BN-heterocycles. Contrary to conventional cis-hydroboration, we demonstrate that the introduction of a pyridyl group switches the stereoselectivity of the reaction. A hydride migration mechanism has been proposed and supported by DFT calculations for the trans-hydroboration. This new hydroboration approach allows facile construction of new blue fluorescent BN-heterocyclic compounds." @default.
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- W2952063743 date "2016-06-01" @default.
- W2952063743 modified "2023-09-27" @default.
- W2952063743 title "ChemInform Abstract: Pyridyl Directed Catalyst-Free trans-Hydroboration of Internal Alkynes." @default.
- W2952063743 cites W2256570036 @default.
- W2952063743 doi "https://doi.org/10.1002/chin.201627204" @default.
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