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• W2952076957 abstract "Treatment of propargylic dithiolanes with nBuLi followed by a carbonyl electrophile yields the corresponding propargylic dithioacetals. Upon treatment with 1 equiv of Fe(acac)3 and excess MeMgI, elimination of SR and OH moieties from 8 affords the corresponding olefins in satisfactory yield. Benzylic dithioacetals behave similarly. The reaction can be considered an alternative of McMurry coupling of two different carbonyl equivalents." @default.
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• W2952076957 date "2007-08-01" @default.
• W2952076957 modified "2023-10-03" @default.
• W2952076957 title "Iron-Promoted Elimination of β-Thioalkoxy Alcohols. Olefination by Coupling of a Carbonyl Group with a Dithioacetal" @default.
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• W2952076957 doi "https://doi.org/10.1021/ol701579f" @default.
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