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- W2952078457 abstract "Oxidative C−H amination of chiral sulfamate esters using achiral Rh-carboxylate catalysts, PhI(OAc)2, and MgO occurs in high yield and with good to excellent diastereocontrol. A number of examples are included to support a proposed transition state model that accounts for the observed stereoinduction. In addition, stereoselective intramolecular aziridination with substituted homoallyl sulfamates is demonstrated and is rationalized through an analogous stereochemical construct." @default.
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- W2952078457 date "2003-11-08" @default.
- W2952078457 modified "2023-10-18" @default.
- W2952078457 title "Stereochemical Models for Rh-Catalyzed Amination Reactions of Chiral Sulfamates" @default.
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- W2952078457 doi "https://doi.org/10.1021/ol035776u" @default.
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