Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952102721> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2952102721 endingPage "no" @default.
- W2952102721 startingPage "no" @default.
- W2952102721 abstract "Abstract The product distribution obtained from Rh(II)-catalyzed decomposition of α-diazoimides derived from glycine methyl ester has been found to be selectively controlled by the proper choice of catalyst. When the reaction was carried out using perfluorinated ligands, the diazoimide cyclized to produce an isomunchnone dipole whose formation could be monitored by NMR spectroscopy. Reaction of the dipole with a trapping agent such as N-phenylmaleimide resulted in the isolation of a 1,3-dipolar cycloadduct in high yield. The product distribution changed dramatically when rhodium(II)-acetate was employed as the catalyst. The products obtained from this reaction were derived from an azabicyclic epoxide intermediate. The catalyst effect can be modulated by the addition of Sc(OTf)3 as a Lewis acid or by using nitromethane as the solvent. Changing the nature of the interacting carbonyl group had little effect on the cyclization pathways." @default.
- W2952102721 created "2019-06-27" @default.
- W2952102721 creator A5002580011 @default.
- W2952102721 creator A5026107815 @default.
- W2952102721 creator A5088716415 @default.
- W2952102721 date "2010-08-03" @default.
- W2952102721 modified "2023-09-26" @default.
- W2952102721 title "ChemInform Abstract: Site Selectivity in the Rhodium(II)-Catalyzed Reaction of α- Diazoimides. Ligand and Substituent Effects." @default.
- W2952102721 cites W1965812169 @default.
- W2952102721 doi "https://doi.org/10.1002/chin.199741153" @default.
- W2952102721 hasPublicationYear "2010" @default.
- W2952102721 type Work @default.
- W2952102721 sameAs 2952102721 @default.
- W2952102721 citedByCount "0" @default.
- W2952102721 crossrefType "journal-article" @default.
- W2952102721 hasAuthorship W2952102721A5002580011 @default.
- W2952102721 hasAuthorship W2952102721A5026107815 @default.
- W2952102721 hasAuthorship W2952102721A5088716415 @default.
- W2952102721 hasConcept C116569031 @default.
- W2952102721 hasConcept C118792377 @default.
- W2952102721 hasConcept C134121241 @default.
- W2952102721 hasConcept C155647269 @default.
- W2952102721 hasConcept C161790260 @default.
- W2952102721 hasConcept C163638829 @default.
- W2952102721 hasConcept C170493617 @default.
- W2952102721 hasConcept C17112743 @default.
- W2952102721 hasConcept C178790620 @default.
- W2952102721 hasConcept C185592680 @default.
- W2952102721 hasConcept C191897082 @default.
- W2952102721 hasConcept C192562407 @default.
- W2952102721 hasConcept C2776920199 @default.
- W2952102721 hasConcept C2777327210 @default.
- W2952102721 hasConcept C2778689049 @default.
- W2952102721 hasConcept C521398313 @default.
- W2952102721 hasConcept C55493867 @default.
- W2952102721 hasConcept C75473681 @default.
- W2952102721 hasConceptScore W2952102721C116569031 @default.
- W2952102721 hasConceptScore W2952102721C118792377 @default.
- W2952102721 hasConceptScore W2952102721C134121241 @default.
- W2952102721 hasConceptScore W2952102721C155647269 @default.
- W2952102721 hasConceptScore W2952102721C161790260 @default.
- W2952102721 hasConceptScore W2952102721C163638829 @default.
- W2952102721 hasConceptScore W2952102721C170493617 @default.
- W2952102721 hasConceptScore W2952102721C17112743 @default.
- W2952102721 hasConceptScore W2952102721C178790620 @default.
- W2952102721 hasConceptScore W2952102721C185592680 @default.
- W2952102721 hasConceptScore W2952102721C191897082 @default.
- W2952102721 hasConceptScore W2952102721C192562407 @default.
- W2952102721 hasConceptScore W2952102721C2776920199 @default.
- W2952102721 hasConceptScore W2952102721C2777327210 @default.
- W2952102721 hasConceptScore W2952102721C2778689049 @default.
- W2952102721 hasConceptScore W2952102721C521398313 @default.
- W2952102721 hasConceptScore W2952102721C55493867 @default.
- W2952102721 hasConceptScore W2952102721C75473681 @default.
- W2952102721 hasIssue "41" @default.
- W2952102721 hasLocation W29521027211 @default.
- W2952102721 hasOpenAccess W2952102721 @default.
- W2952102721 hasPrimaryLocation W29521027211 @default.
- W2952102721 hasRelatedWork W1985307220 @default.
- W2952102721 hasRelatedWork W1993291615 @default.
- W2952102721 hasRelatedWork W2008623728 @default.
- W2952102721 hasRelatedWork W2022121535 @default.
- W2952102721 hasRelatedWork W2050432159 @default.
- W2952102721 hasRelatedWork W2075749663 @default.
- W2952102721 hasRelatedWork W2082764470 @default.
- W2952102721 hasRelatedWork W2166567537 @default.
- W2952102721 hasRelatedWork W2340633478 @default.
- W2952102721 hasRelatedWork W2949117441 @default.
- W2952102721 hasRelatedWork W2949526691 @default.
- W2952102721 hasRelatedWork W2949619710 @default.
- W2952102721 hasRelatedWork W2949898541 @default.
- W2952102721 hasRelatedWork W2951507553 @default.
- W2952102721 hasRelatedWork W2999194351 @default.
- W2952102721 hasRelatedWork W3163454531 @default.
- W2952102721 hasRelatedWork W53524911 @default.
- W2952102721 hasRelatedWork W776868732 @default.
- W2952102721 hasRelatedWork W2814918111 @default.
- W2952102721 hasRelatedWork W2933066936 @default.
- W2952102721 hasVolume "28" @default.
- W2952102721 isParatext "false" @default.
- W2952102721 isRetracted "false" @default.
- W2952102721 magId "2952102721" @default.
- W2952102721 workType "article" @default.