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- W2952116601 abstract "Abstract Fluorination of C 60 (s), C 60 (s)–MnF 2 (s), C 60 (s)–NiF 2 (s) and C 60 (s)–MnF 3 (s) mixtures has been studied by Knudsen cell mass spectrometry with admission of molecular fluorine. The fluorination is selective when fullerene reacts with the fluorine chemisorbed on the MnF 2 surface. When the MnF 2 content in the initial mixture is at least 90 mol% both C 60 F 18 and C 60 F 36 are selectively formed. Under certain conditions, mixtures predominantly containing one of three compounds C 60 F 38 , C 60 F 40 , and C 60 F 42 can be obtained. A consecutive change of the main fluorination products (C 60 F 18 and C 60 F 36 ) takes place at constant temperature (720 K) and on fluorine admission. A quantitative explanation of this fact is given. Selective fluorination of C 60 (s) by molecular fluorine is compared with solid-phase fluorination using MnF 3 (s) as a fluorinating agent." @default.
- W2952116601 created "2019-06-27" @default.
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- W2952116601 date "2010-05-21" @default.
- W2952116601 modified "2023-09-27" @default.
- W2952116601 title "ChemInform Abstract: Selective Formation of C60F18(g) and C60F36(g) by Reaction of [60]Fullerene with Molecular Fluorine." @default.
- W2952116601 cites W2163003268 @default.
- W2952116601 doi "https://doi.org/10.1002/chin.200226113" @default.
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