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- W2952152065 abstract "Department of Chemistry, Gyeongsang National University, Chinju 660-701, KoreaReceived October 10, 2012, Accepted November 29, 2012Optically active N-benzyl-2-methyl-2H-benzo[b][1,4]oxazin-3(4H)-ones and N-benzyl-2-methyl-2H-benzo[b][1,4]thiazin-3(4H)-ones with potential synthetic and pharmacological interest were prepared via Smilesrearrangement in conventional as well as microwave irradiation conditions in one-pot from inexpensive ( S)-2-chloropropionic acid. Most of the compounds displayed good inhibition against Gram positive bacteria andfungi in the antibiotic test.Key Words : Oxazinones, Thiazinones, Smiles rearrangement, Microwave irradiation, AntibioticIntroduction1,4-Benzoxazinones and 1,4-benzothiazinones are fasci-nating tools present in clinically significant pharmaceuticalsand other biologically active molecules. Compounds con-taining 2H-benzo[b][1,4]-oxazin-3(4 H)-one moiety are wellknown to show wide biological activities such as beingantiulcer," @default.
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- W2952152065 date "2013-02-20" @default.
- W2952152065 modified "2023-10-12" @default.
- W2952152065 title "Microwave Synthesis of Chiral N-Benzyl-2-methyl-2H-benzo[b][1,4]oxazin/thiazin-3(4H)-ones via Smiles Rearrangement and their Biological Evaluation" @default.
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