Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952153344> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2952153344 abstract "The structure of the title compound was solved from diffractometer data by the heavy-atom method and refined by least-squares techniques to R= 0.056 for 585 observed reflections. Crystals are monoclinic, space group C2, with unit-cell dimensions a= 21.424(6), b= 4.668(2), c= 6.734(3)A, β= 90.45(5)°, and Z= 2. For each asymmetric unit there are two crystallographically independent mercury atoms. One of them bonds covalently to two sulphur atoms at 2.378 A, and four chlorine atoms with long contacts (2.985 and 3.342 A). The co-ordination around the other mercury atom involves two chlorine atoms at 2.534 A and two sulphur atoms at 2.537 A. The geometry of the polymeric structure is consistent with i.r. and Raman data. The low values of ν(Hg–S)(231 cm–1) and ν(Hg–Cl)(218 cm–1) reflect the interactions of ligand groups in the crystal. Spectroscopic results suggest two types of dissociation pathways on dissolving in pyridine, to form the species Hg(SPri)Cl, Hg(SPri)2, and HgCl2, and corresponding pyridine adducts." @default.
- W2952153344 created "2019-06-27" @default.
- W2952153344 creator A5005020021 @default.
- W2952153344 creator A5005894401 @default.
- W2952153344 creator A5079147626 @default.
- W2952153344 date "1984-08-21" @default.
- W2952153344 modified "2023-09-26" @default.
- W2952153344 title "ChemInform Abstract: ORGANOTHIOMETALLIC COMPOUNDS. CRYSTAL STRUCTURE AND SPECTROSCOPIC PROPERTIES OF (ISOPROPYLTHIO)MERCURY(II) CHLORIDE" @default.
- W2952153344 cites W2038663787 @default.
- W2952153344 doi "https://doi.org/10.1002/chin.198434058" @default.
- W2952153344 hasPublicationYear "1984" @default.
- W2952153344 type Work @default.
- W2952153344 sameAs 2952153344 @default.
- W2952153344 citedByCount "0" @default.
- W2952153344 crossrefType "journal-article" @default.
- W2952153344 hasAuthorship W2952153344A5005020021 @default.
- W2952153344 hasAuthorship W2952153344A5005894401 @default.
- W2952153344 hasAuthorship W2952153344A5079147626 @default.
- W2952153344 hasConcept C108204754 @default.
- W2952153344 hasConcept C115624301 @default.
- W2952153344 hasConcept C149635348 @default.
- W2952153344 hasConcept C155647269 @default.
- W2952153344 hasConcept C178790620 @default.
- W2952153344 hasConcept C185592680 @default.
- W2952153344 hasConcept C199360897 @default.
- W2952153344 hasConcept C205188671 @default.
- W2952153344 hasConcept C2777777548 @default.
- W2952153344 hasConcept C2779485729 @default.
- W2952153344 hasConcept C39546656 @default.
- W2952153344 hasConcept C41008148 @default.
- W2952153344 hasConcept C58312451 @default.
- W2952153344 hasConcept C61276311 @default.
- W2952153344 hasConcept C8010536 @default.
- W2952153344 hasConceptScore W2952153344C108204754 @default.
- W2952153344 hasConceptScore W2952153344C115624301 @default.
- W2952153344 hasConceptScore W2952153344C149635348 @default.
- W2952153344 hasConceptScore W2952153344C155647269 @default.
- W2952153344 hasConceptScore W2952153344C178790620 @default.
- W2952153344 hasConceptScore W2952153344C185592680 @default.
- W2952153344 hasConceptScore W2952153344C199360897 @default.
- W2952153344 hasConceptScore W2952153344C205188671 @default.
- W2952153344 hasConceptScore W2952153344C2777777548 @default.
- W2952153344 hasConceptScore W2952153344C2779485729 @default.
- W2952153344 hasConceptScore W2952153344C39546656 @default.
- W2952153344 hasConceptScore W2952153344C41008148 @default.
- W2952153344 hasConceptScore W2952153344C58312451 @default.
- W2952153344 hasConceptScore W2952153344C61276311 @default.
- W2952153344 hasConceptScore W2952153344C8010536 @default.
- W2952153344 hasLocation W29521533441 @default.
- W2952153344 hasOpenAccess W2952153344 @default.
- W2952153344 hasPrimaryLocation W29521533441 @default.
- W2952153344 hasRelatedWork W1971335709 @default.
- W2952153344 hasRelatedWork W1972127895 @default.
- W2952153344 hasRelatedWork W1978468291 @default.
- W2952153344 hasRelatedWork W1990934658 @default.
- W2952153344 hasRelatedWork W2002006646 @default.
- W2952153344 hasRelatedWork W2038663787 @default.
- W2952153344 hasRelatedWork W2039710833 @default.
- W2952153344 hasRelatedWork W2068573987 @default.
- W2952153344 hasRelatedWork W2072850834 @default.
- W2952153344 hasRelatedWork W2091961213 @default.
- W2952153344 hasRelatedWork W2107623416 @default.
- W2952153344 hasRelatedWork W2130421359 @default.
- W2952153344 hasRelatedWork W2140415921 @default.
- W2952153344 hasRelatedWork W2163337014 @default.
- W2952153344 hasRelatedWork W2523288196 @default.
- W2952153344 hasRelatedWork W2950885951 @default.
- W2952153344 hasRelatedWork W2950983538 @default.
- W2952153344 hasRelatedWork W2952176209 @default.
- W2952153344 hasRelatedWork W2953149151 @default.
- W2952153344 hasRelatedWork W2953315681 @default.
- W2952153344 isParatext "false" @default.
- W2952153344 isRetracted "false" @default.
- W2952153344 magId "2952153344" @default.
- W2952153344 workType "article" @default.